WebMar 28, 2024 · Polymers containing cyclic derivatives are a new class of macromolecular topologies with unique properties. Herein, we report the synthesis of a triblock copolymer containing a spirocyclic mid-block. To achieve this, a spirocyclic polystyrene (cPS) mid-block was first synthesized by atom transfer radical polymerization (ATRP) using a tetra … Webthe design and development of cyclic polymer with an empha-sis on its synthesis and bio-related properties and applications. Two primary synthetic strategies towards cyclic polymers, that is, ring-expansion polymerization and ring-closure reaction are summarized. The bioproperties and biomedical applications of cyclic polymers are then highlighted.
Polymers Free Full-Text A Critical Review on Polymeric …
WebCyclic polymers have long been reported in the literature, but their development has often been stunted by synthetic difficulties such as the presence of linear contaminants. … WebIn this work, we design the amphiphilic peptoid polymers by mimicking the positively charged and hydrophobic structures of HDPs and synthesize a series of cyclic peptoid polymers efficiently via the polymerization on α-amino acid N-substituted glycine N-carboxyanhydrides (α-NNCAs) using 1,8-diazabicycloundec-7-ene (DBU) as the initiator. bts tecnologia
Polymers Special Issue : Polymeric Biomaterials and Drug …
WebSep 13, 2024 · The review also highlights some of the unique physical properties of cyclic polymers together with potential applications. The findings illustrate the substantial … WebFeb 26, 2024 · The tuning of degradation kinetics using, for example, copolymerization, blending, polymer architecture, or additives, is required for making polymers suitable for specific applications. This is nothing new but is the same strategy as that applied for the use of biodegradable polymers as biomaterials for biomedical applications. WebJun 21, 2013 · Cyclic polymers are an intriguing class of macromolecules. Because of the constraints of the cyclic topology and the absence of chain ends, the properties of these molecules differ from those of linear polymers in ways that remain poorly understood. Cyclic polymers present formidable synthetic challenges because the entropic penalty … expedia the grove resort and spa